Английский словарь Webster - un- (8)

(adv.) Those which have the value of independent words, inasmuch as the simple words are either not used at all, or are rarely, or at least much less frequently, used; as, unavoidable, unconscionable, undeniable, unspeakable, unprecedented, unruly, and the like; or inasmuch as they are used in a different sense from the usual meaning of the primitive, or especially in one of the significations of the latter; as, unaccountable, unalloyed, unbelieving, unpretending, unreserved, and the like; or inasmuch as they are so frequently and familiarly used that they are hardly felt to be of negative origin; as, uncertain, uneven, and the like.